| . | Oxidation of Aromatic Moieties
(4th or para position attachment of OH) |
| . | Oxidation of Olefinic Bonds
(Double bond broken to two OH)
(Epoxide Hydrolase) |
| . | Oxidation of Olefinic Bonds
(Double bond broken to two OH)
(Epoxide Hydrolase) |
| . | Benzylic Carbon Hydroxylation
(Stearic Hindrance)
(Attach OH to carbon attached to an aromatic ring or phenol group) |
| . | Benzylic Carbon Hydroxylation
(Stearic Hindrance)
(Attach OH to carbon attached to an aromatic ring or phenol group) |
| . | Oxidation of Allylic Carbon Atoms
(Attachment of OH to --> C-C=C (allylic)) |
| . | Oxidation of Allylic Carbon Atoms
(Attachment of OH to --> C-C=C (allylic)) |
| . | Oxidation of Allylic Carbon Atoms
(Attachment of OH to --> C-C=C (allylic)) |
| . | Hydroxylation at Cα to C=O and C=N
(Attachment of OH to the carbon next to the C=O or C=N) |
| . | Hydroxylation at Cα to C=O and C=N
(Attachment of OH to the carbon next to the C=O or C=N) |
| . | Aliphatic Hydroxylation
(Attachment to the 2nd to the last or last carbon in a straight chain group) |
| . | Aliphatic Hydroxylation
(Attachment to the 2nd to the last or last carbon in a straight chain group) |
| . | Aliphatic Hydroxylation
(Attachment to the 2nd to the last or last carbon in a straight chain group) |
| . | Alicyclic (nonaromatic) Hydroxylation
(Attachment to 3rd (if there is substituent) or 4th carbon in a nonaromatic cyclic) |
| . | Alicyclic (nonaromatic) Hydroxylation
(Attachment to 3rd (if there is substituent) or 4th carbon in a nonaromatic cyclic) |
| . | Oxidation Involving Carbon-Heteroatom Systems
Hydroxylation of alpha-C
(CN, CS, CO) |
| . | Oxidation Involving Carbon-Heteroatom Systems
N-dealkylation
(CN, CS, CO) |
| Alicyclic 3˚ Amines often generates __ | Lactams |
| . | Deamination |
| . | N-oxidation of aromatic amines |
| . | N-oxidation of primary amines |
| . | N-oxidation of secondary amines |
| . | N-oxidation of tertiary amines |
| . | Alpha C hydroxylation of amides
or N-hydroxylation |
| Oxidation involving C-O system converts __ to __ | 1 ether
2 alcohol + ketone or aldehyde |
| . | Oxidation involving C-O system
(ether turns into alcohol and ketone or aldehyde) |
| . | Oxidation involving C-S System
S-dealkylation |
| . | Oxidation involving C-S System
Desulfuration |
| . | Oxidation involving C-S System
S-oxidation |
| . | Oxidative Dehalogenation
(When there are two halogens) |
| Alcohol turns into __
Aldehyde turns into __
Secondary alcohol turns into __ | 1 aldehyde
2 carboxylic acid
3 Ketone |
| . | Desulfuration |
